Jatropholane and crotopholane diterpenoids

Description:

Diterpenoids with a structure based either on the jatropholane or the crotopholane skeleton. Jatropholanes arise by 5,13- and 6,10-cyclisation of a casbane precursor. Subsequent cleavage of the 2,15-cyclopropane bond affords crotofolane.
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