(R)-Ru(OAc)₂(BINAP) - ≥97% , CAS No.325146-81-4

CAS: 325146-81-4 Cat. No.: R138672 Molecular Weight: 841.83 EC Number: 815-432-2 PubChem CID: 11083409

GRADE & PURITY ≥97%

Synonyms

F16636 | Ru(BINAP)(OAc)2 | DIACETATO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II) | Diacetato[(S)-()-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) | SY010589 | (S)-Ru(OAc)2(BINAP | acetic acid;[1-(2-diphenylphosphanylnapht

Storage

Store at 2-8°C,Protected from light,Argon charged

Shipped In

Wet ice

Overview

Product Description
1.Catalyst system that exhibits very high catalytic activity and enantioselectivity in the hydrogenation of a wide range of substrates.
Product class
M-P, Homogeneous Catalysts, M-O, Acetate Ligands, Phosphorus Ligands - Chiral

Reaction type
Hydrogenation, Asymmetric Reactions, Asymmetric Hydrogenation, Transfer Hydrogenation

Chemical properties

Chemical formula

C48H38O4P2Ru

Empirical formula

Ru[(R)-BINAP](OAc)2

Molecular weight

841.84

Metal

Ru

Theoretical metal content

12

Physical state

powder

Color

tan

Applications & references

Asymmetric hydrogenation of ß-ketoester for the enantioselective synthesis of (R)-d-lactones.

Reference: WO2001 057014

Enantioselective synthesis of levetiracetam including asymmetric hydrogenation of (Z)-2-(2-oxopyrrolidin-1-yl)but-2-enamide.  

Reference: WO2001 064637

Synthesis of (S)-fluoromethyldihydro-furan-2-one for the manufacture of pyrido[2,1-a]isoquinoline derivatives which are useful for treatment or prophylaxis of diseases.

Reference: WO2006 125728

Asymmetric hydrogenation of five-membred α,β-unsaturated carbonyl compounds.

Reference: J. Org. Chem. 1995, 60, 357 (DOI: 10.1021/jo00107a014)

Specifications

Synonyms

F16636 | Ru(BINAP)(OAc)2 | DIACETATO[(S)-(-)-2, 2'-BIS(DIPHENYLPHOSPHINO)-1, 1'-BINAPHTHYL]RUTHENIUM(II) | Diacetato[(S)-()-2, 2'-bis(diphenylphosphino)-1, 1'-binaphthyl]ruthenium(II) | SY010589 | (S)-Ru(OAc)2(BINAP | acetic acid;[1-(2-diphenylphosphanylnapht

Specifications & Purity

≥97%

Storage

Store at 2-8°C, Protected from light, Argon charged

Shipped In

Wet ice

This product requires cold chain shipping. Ground and other economy services are not available.

Purity

≥97%

Names and Identifiers

• Canonical Smiles: CC(=O)O.CC(=O)O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru]
• IUPAC Name: acetic acid;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium
• InChIKey: XANQJWCSQJDBEA-UHFFFAOYSA-N
• INCHI: 1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4)
• Isomeric SMILES: CC(=O)O.CC(=O)O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru]
• PubChem CID: 11083409
• Molecular Weight: 841.83

Chemical and Physical Properties

• Sensitivity: Light Sensitive,Air Sensitive;Moisture sensitive