Technical articles

A Panoramic Guide to Silicone Materials: Structural Mechanisms, Core Properties, Value Chain, and Product Categories

What Are Organosilicon / Silicone Materials?

1. Silicon and Inorganic Silicon Compounds

Silicon (Si) is one of the most abundant elements in the Earth’s crust, second only to oxygen. In nature, silicon mainly exists in inorganic forms such as silicates and silicon dioxide, found in rocks, sand, crystals, glass, and ceramics. For thousands of years, humans have utilized inorganic silicon materials to produce traditional products such as cement, ceramics, and glass, forming the foundation of construction and daily life.

2. Concept of Organosilicon

Unlike inorganic silicon, organosilicon (organosilicon compounds) refers to a broad class of compounds that contain both silicon–carbon (Si–C) bonds and organic groups within the molecule.

  • Organosilicon compounds: Typically refer to “silicon compounds containing at least one Si–C bond.”
  • Siloxanes: Emphasize the structural unit –Si–O–Si– (including oligomers such as D3/D4 as well as polymers).
  • Silicones / silicone rubber / silicone fluids (oils) / silicone resins: In engineering and commercial contexts, these typically refer to “a family of material systems primarily based on polysiloxanes” (including fluids, elastomers, resins, etc.).

Organosilicon compounds were progressively synthesized and developed during the 20th century, with industrial production beginning in the 1940s. Since then, owing to their distinctive properties, silicones have rapidly spread across electronics, electrical engineering, construction, automotive, personal care, healthcare, and everyday consumer products. They are sometimes referred to as “the monosodium glutamate of industry”—not necessarily used in large amounts, but almost ubiquitous.

Structure and Core Properties of Silicones

1. Structural Features: Combining Advantages of “Glass” and “Plastics”

The main chain of typical silicone polymers (e.g., polydimethylsiloxane, PDMS) is –Si–O–Si–, while the backbone of common organic polymers (e.g., polyethylene, polypropylene) is –C–C–.

(1) High Si–O bond energy, more stable than C–C bonds → excellent heat resistance, oxidation resistance, and weatherability

(2) Large Si–O–Si bond angle and flexible chain segments → softness, low glass transition temperature (Tg), and a wide elastic working range

(3) Organic groups attached to silicon (methyl, phenyl, vinyl, fluoroalkyl, etc.) can tune hydrophobicity, flexibility, electrical properties, and low-temperature performance

Conceptually, the backbone is a siloxane framework with partial inorganic character (stable and weather-resistant), while the side groups are organic (providing flexibility and processability). With further crosslinking (e.g., silicone resins or vulcanized silicone rubber), the structure becomes closer to a “network-like” architecture.

2. Overview of Key Properties

These structural features confer a set of characteristic properties:

(1) Outstanding high- and low-temperature resistance: Typical silicone rubber can be used long-term at approximately –60 to 200 °C; special formulations can retain performance under more demanding conditions.

(2) Excellent weatherability: Highly stable against UV, ozone, humidity, acid rain, and other environmental factors; long-term outdoor use is less prone to chalking, cracking, or loss of elasticity.

(3) Good flexibility and elasticity: After stretching, compression, or bending, the material can recover well—especially suitable for sealing, cushioning, and vibration damping.

(4) Hydrophobicity and water resistance: Most silicones present low-polarity organic groups (e.g., methyl) at the surface, resulting in low surface energy and large contact angles, effectively providing water and moisture resistance.

(5) Excellent electrical insulation: Stable dielectric constant and volume resistivity across wide temperature and humidity ranges; suitable for insulating potting/encapsulation and insulating coatings.

(6) Chemical and biological inertness: Generally not reactive with many substances; certain grades exhibit good biocompatibility and can be used in medical and care applications (e.g., contact lenses, medical tubing, skin-contact materials).

Note: Swelling may occur in fuels/solvents; degradation may occur under strong acids/alkalis or harsh hydrothermal conditions; medical use must meet relevant biocompatibility and regulatory requirements.

(7) Surface-tuning capability: Silicone surface tension can be readily adjusted:

  • As surfactants, they can improve wetting, leveling, and crater prevention;
  • As mold-release or release agents, they can reduce adhesion for easy demolding/peeling.

These attributes make silicones indispensable functional materials in many applications.

Remarks:

  • Chemical resistance is not universal: Most silicones are stable to water and mild acids/bases, but may degrade in strong acids/alkalis or strongly oxidative systems; PDMS may swell in nonpolar solvents/fuels/certain oils (one reason why fluorosilicones and FKM exist).
  • “Biological inertness/medical use”: Only medical-grade materials that pass relevant regulations and biocompatibility testing are suitable for long-term human contact.
  • Electrical/mechanical performance depends on formulation and environment: Fillers, flame retardants, moisture uptake, and contamination can significantly affect dielectric properties and volume resistivity.

Silicone Industry Value Chain and Major Products (From Feedstocks to End Use)

1. Three-Tier Overview of the Silicone Value Chain

From a value-chain perspective, silicones can be broadly divided into three tiers: silicone monomers → silicone intermediates → silicone polymers and formulated products. The table below shows their relationships and typical examples, helping establish a complete picture from upstream feedstocks to end-use materials.

Value-chain tier

Typical representative substances

Main sources / formation routes

Main downstream product categories

Common forms in lab/application

Silicone monomers

Organochlorosilanes: dimethyldichlorosilane, methyltrichlorosilane, phenyltrichlorosilane, vinyltrichlorosilane, 3-chloropropyltrichlorosilane, etc.

Starting from metallurgical silicon; via the Direct Process and related routes to produce mainly methylchlorosilanes as base monomers; other functional silanes are typically obtained by further functionalization of base monomers. These are foundational upstream feedstocks for the silicone industry.

Linear/cyclic siloxane oligomer intermediates; further used to produce silicone fluids, silicone rubber, silicone resins, silane coupling agents, etc.

Monomer reagents and coupling-agent precursors, commonly used in synthesis and mechanistic studies

Silicone intermediates

Linear/cyclic siloxane oligomers: hexamethyldisiloxane (HMDSO), hexamethylcyclotrisiloxane (D), octamethylcyclotetrasiloxane (D), dimethyl cyclosiloxane mixtures (DMC), etc.

Low-molecular-weight siloxanes obtained via hydrolysis, condensation, or cracking of monomers

Polymerized into long-chain polysiloxanes to form silicone fluids, silicone rubber, silicone resins, etc., with different viscosities/functionalities

Oligomeric siloxanes used as monomers/intermediates for further polymerization or modification

Silicone polymers & formulated products

Polysiloxanes and formulated products: silicone rubber, silicone fluids and modified silicone fluids, silicone resins, silane coupling agents, silicone gels and potting/encapsulation compounds, silicone pressure-sensitive adhesives (PSA) and release coatings, specialty fluorosilicone materials, etc.

Based on intermediates; produced via polymerization and crosslinking, formulated with fillers, catalysts, additives, and other components

End-use structural and functional materials; the most commonly encountered in research, education, and engineering applications

RTV silicone rubbers, silicone fluids (various viscosities), silicone resin solutions, coupling agents, potting compounds, defoamers, coatings, PSA, release agents, etc.

2. Major Silicone Product Categories

2.1 Silicone Rubber (Silicone Elastomers)

Concept and features

Silicone rubber is an elastomer with a polysiloxane backbone. Among synthetic rubbers, it offers an exceptionally wide service temperature range and combines:

  • Excellent high- and low-temperature resistance
  • Good weathering, radiation, ozone, and damp-heat resistance
  • Good electrical insulation and biological inertness

Typical applications: O-rings, gaskets, conductive keypads, medical tubing, kitchenware, baby products, wire and cable jackets, high-temperature seals, etc.

Classification by curing temperature / form

1. High-Temperature Vulcanized Silicone Rubber (HTV / HCR)

Based on high-molecular-weight gum, compounded with reinforcing fillers and peroxide or addition-curing crosslinkers, and vulcanized via high-temperature molding, extrusion, etc.

Commonly used for cable jackets, high-temperature seals, household appliance parts, etc.

2. Room-Temperature Vulcanized Silicone Rubber (RTV)

Based on low- to medium-molecular-weight, end-functional polysiloxanes; cures without high temperature.

  • One-component RTV (RTV-1): Moisture-cures in air; commonly used for sealing and bonding glass, metals, and plastics.
  • Two-component RTV (RTV-2): Cures after mixing components A and B at room or moderate temperature; suitable for potting, mold making, replication, etc.

3. Liquid Silicone Rubber (LSR)

Typically a two-component, addition-curing liquid system with good flowability, suitable for liquid injection molding (LIM) and fast curing at moderate or elevated temperature.

Commonly used for baby pacifiers, medical parts, keyboard covers, and high-requirement seals with complex shapes.

Brief classification by curing mechanism

  • Peroxide-initiated crosslinking: Conventional high-temperature curing; mature process and broad applicability.
  • Condensation curing: Involves moisture/hydroxyl participation and releases small-molecule byproducts (e.g., alcohols, oximes); common in certain RTV systems.
  • Addition curing: Platinum-catalyzed hydrosilylation between Si–H and vinyl groups; no small-molecule byproducts, low shrinkage, good electrical properties; widely used in high-end encapsulation, mold making, and LSR.

2.2 Silicone Fluids and Modified Silicone Fluids, Emulsions, and Surfactants

Basic concept of silicone fluids

Silicone fluids are polysiloxanes that are flowable liquids at room temperature, generally linear in structure. Viscosity ranges from very low (near water) to very high (grease-like). Typical examples include:

  • Methyl silicone fluid: the most widely used
  • Methyl phenyl silicone fluid: improved high/low-temperature performance
  • Functional silicone fluids containing amino, hydroxyl, epoxy, and other groups

Key properties of silicone fluids:

  • Low viscosity–temperature coefficient; good heat/cold resistance and oxidation resistance
  • Low surface tension; good lubricity, anti-stick, and mold-release performance
  • Good electrical insulation; low corrosivity toward metals
  • Many grades are colorless, odorless, and low in toxicity

Modified silicone fluids, emulsions, and surfactants

By introducing hydrophilic/lipophilic groups such as polyethers onto silicone chains, various modified silicone fluids and silicone surfactants can be obtained:

1. Polyether-modified silicone fluids: Combine low surface tension of silicone with hydrophilicity of polyethers; can form stable emulsions and are widely used in:

  • Textile softeners and finishing agents
  • Coating leveling agents and anti-crater additives
  • Pesticide/agricultural adjuvants, etc.

2. Silicone emulsions: Silicone fluids emulsified in water for easier formulation (e.g., leather finishing, anti-fog glass treatments, water-repellent coatings).

3. Silicone defoamers: Typically silicone fluids combined with hydrophobic particles; provide fast foam knockdown and foam suppression, used in:

  • Fermentation, papermaking, coatings, cleaning, wastewater treatment, and related systems.

Typical applications

1. Lubrication, anti-stick, waterproofing, and moisture resistance

2. Defoamers, mold-release agents, polishing agents

3. Hand-feel improvement and finishing for textiles, leather, and paper

4. Conditioning and film-forming agents in personal care (hair care, sunscreens, color cosmetics)

2.3 Silicone Resins (Silicone Resins)

Structure and features

Silicone resins are highly crosslinked, semi-inorganic polymers with a –Si–O–Si– backbone and organic substituents on silicon.

1. Resin-like intermediates are produced via hydrolysis and condensation of multifunctional organosilanes, followed by further crosslinking under heat or catalysis to form an infusible, insoluble thermoset three-dimensional network.

2. Common structural units include T units (RSiO/) and Q units (SiO/). (Silicone resins are typically obtained by hydrolysis/condensation of multifunctional silanes to form resins/intermediates; during application or upon heating/catalysis, further crosslinking occurs. After curing, an infusible/insoluble network forms. Structural units are often described using M/D/T/Q notation, where T and Q determine the crosslinked backbone.)

Key properties:

1. Good heat resistance: suitable for long-term use at elevated temperatures

2. Excellent weatherability and UV resistance

3. Stable dielectric properties

4. Good performance in water resistance, anti-mildew, smoke resistance, arc resistance, radiation resistance, etc.

Applications

1. Insulating varnishes, impregnation varnishes, and encapsulating varnishes for motors and electrical devices

2. High-temperature coatings, weather-resistant architectural coatings, powder coatings

3. Water-repellent penetrating coatings

4. Components in high-temperature adhesives and heat-resistant bonding systems

2.4 Silanes and Silane Coupling Agents

Basic structure and concept

Many silane coupling agents can be expressed by the general formula:

Y–R–SiX

  • X: Hydrolyzable groups (e.g., –Cl, –OCH, OCH), which can react with or strongly bond to inorganic surfaces such as glass, silica, metal oxides, and mineral fillers.
  • Y: Organic reactive groups (e.g., vinyl, epoxy, amino, methacryloxy), which can react with or strongly bond to organic polymers such as resins and rubbers.
  • R: A linking group (alkyl, aryl, etc.).

Because the molecule contains both an inorganic-affinitive part and an organic-affinitive part, silane coupling agents act as a “bridge” at inorganic/organic interfaces, significantly improving adhesion and interfacial performance.

Applications

  • Glass fiber surface treatment in fiber-reinforced plastics (FRP)
  • Surface treatment of fillers (e.g., fumed silica, talc, calcium carbonate) to improve dispersion and interfacial bonding in resins
  • Improving adhesion to substrates such as glass, metals, and concrete in sealants and structural adhesives
  • Water repellents and protective agents for stone and concrete surfaces
  • Special surface functionalization: antistatic, anti-mildew, anti-fouling, anti-thrombogenic, etc.

2.5 Silicone Gels and Encapsulation (Potting) Materials

Silicone gel (Silicone Gel)

Silicone gel lies between a liquid and a solid elastomer and typically appears as a soft gel-like material with:

  • Excellent electrical insulation and energy-absorbing cushioning properties
  • Good gap-filling capability, buffering thermal expansion/contraction and mechanical shock

It is commonly used for internal protection of devices where maintainability and reworkability are required.

Silicone potting/encapsulation compounds

Potting compounds are typically two-component systems (addition-cure or condensation-cure) and can be formulated as:

  • Soft type (gel-like): Suitable for protecting delicate components while also requiring heat dissipation
  • Elastomeric type: Provides higher mechanical strength and environmental protection

They can also be formulated as thermally conductive, flame-retardant, high-temperature-resistant types, etc.

Application areas:

  • Potting and encapsulation for electronic components, power modules, transformers, and coils
  • LED drivers and lighting modules
  • Power electronics protection in photovoltaics and energy storage systems
  • Protection for sensors, ignition coils, and other devices operating long-term outdoors or in high-temperature environments

2.6 Silicone Pressure-Sensitive Adhesives and Release Coatings

In tapes, labels, and protective films, silicones mainly appear in two forms:

1. Silicone pressure-sensitive adhesives (Silicone PSA)

  • Maintain tack and peelability across wide temperature ranges; good aging resistance
  • Used for high-temperature tapes, electrical insulation tapes, protective films, etc.

2. Silicone release coatings (Release Coatings)

  • Applied on release papers/films to provide stable, controllable release force
  • Used as the “release liner” layer for labels, double-sided tapes, die-cut parts, protective films, etc.

2.7 Specialty Silicones and Silicone–Organic Hybrids

To meet specific service environments, silicones have developed many specialty branches:

1. Fluorosilicone rubber and fluorosilicone fluids

Fluorinated organic groups are introduced onto siloxane chains, combining resistance to oils, fuels, solvents, and weathering.

Used in harsh environments such as aerospace, oil and gas extraction, and automotive fuel systems for seals and lubrication systems.

2. Silicone–organic hybrids and silicone-modified resins

By introducing silanes or siloxane structures into organic resins (e.g., acrylics, polyurethanes, epoxies), materials such as:

  • Silicone-modified acrylic resins
  • Silicone-modified polyurethanes
  • Silane-modified polyethers (MS Polymer), etc.

can be formed, significantly improving weatherability, water resistance, adhesion, and flexibility of coatings and sealants.

3. Specialty silicone fluids for personal care

Such as volatile silicones, network film-forming silicones, and ultra-slippery silicone fluids, widely used in sunscreens, color cosmetics (long-wear, waterproof), skincare, and haircare to deliver excellent skin feel and hair feel.

Note: Regulatory requirements for certain cyclic volatile siloxanes differ by region; formulation development should be evaluated against local compliance requirements and restricted-substance lists.

Representative Aladdin Silicone and Related Silicon-Based Products (Selected Examples)

Based on Aladdin’s current product portfolio, selected representative items are summarized by “product category + typical application,” covering organosilicon monomers, silicone intermediates, silicone fluids/hydrogen silicone fluids, silica materials, and elemental silicon series. This table lists only some typical catalog numbers from Aladdin’s silicone family to help illustrate the roles and features of different silicone material types in research and formulation development. Available grades, specifications, purities, and packaging options are more extensive. You are welcome to search the Aladdin website by CAS number or product reference number for more information and to match your specific experimental needs.

Category

CAS No.

Aladdin Cat. No.

Product name

Specification / Purity

Key features / applications

Organosilicon monomers / functional silanes

4420-74-0

M100619

(3-Mercaptopropyl)trimethoxysilane

≥95%

Mercapto silane coupling agent; metal surface modification; thiol-click reaction functionalization

Organosilicon monomers / functional silanes

2530-85-0

S111153

3-(Isobutenoyloxy)propyltrimethoxysilane

≥97%, contains 100 ppm BHT stabilizer

Methacrylate-functional silane; coupling agent for acrylic resins and UV-curable systems

Organosilicon monomers / functional silanes

919-30-2

A107147

3-Aminopropyltriethoxysilane (APTS)

≥99%

Amino silane coupling agent; high-purity APTS for surface modification of fillers/glass, etc.

Organosilicon monomers / functional silanes

2550-06-3

C153383

3-Chloropropyltrichlorosilane

≥97% (GC)

Intermediate for chloropropyl-functional silanes and modified resin intermediates

Organosilicon monomers / functional silanes

2530-83-8

G107576

3-Glycidyloxypropyltrimethoxysilane

≥97%

Epoxy silane coupling agent; used in epoxy resins and electrical encapsulation, etc.

Organosilicon monomers / functional silanes

75-94-5

T162726

Vinyltrichlorosilane

≥98% (GC)

Introduces vinyl groups for HTV rubber and resin crosslinking

Organosilicon monomers / functional silanes

78-08-0

T103647

Vinyltriethoxysilane (TEVS)

≥97%

Vinyltriethoxysilane (TEVS); crosslinker/coupling agent

Organosilicon monomers / functional silanes

2768-02-7

V162969

Vinyltrimethoxysilane

≥98% (GC)

Vinyltrimethoxysilane (VTMS); crosslinker/coupling agent

Organosilicon monomers / functional silanes

107-37-9

A337178

Allyltrichlorosilane

≥95%

Introduces unsaturated double bonds for copolymerization modification

Organosilicon monomers / functional silanes

18151-53-6

T162725

1,1,2-Trimethylpropyltrichlorosilane

≥96% (GC)

Branched-alkyl trichlorosilane; for silicone resins and hydrophobic surface modification

Organosilicon monomers / functional silanes

6233-20-1

C694712

2-Chloroethyltrichlorosilane

≥95%

Intermediate for subsequent grafting and functionalization

Organosilicon monomers / functional silanes

141-57-1

T118547

Propyltrichlorosilane

≥99%

Propyl-substituted silicone resin / hydrophobic treatment monomer

Organosilicon monomers / functional silanes

75-79-6

M104828

Methyltrichlorosilane

≥99%

Base monomer for silicone resins and crosslinkers

Organosilicon monomers / functional silanes

98-13-5

T113245

Phenyltrichlorosilane

≥98%

Introduces phenyl groups to improve heat resistance and refractive index

Organosilicon monomers / functional silanes

54076-73-2

N336595

Norbornenyl ethyl trichlorosilane

≥95%

Specialty unsaturated functional monomer

Organosilicon monomers / base monomers

75-78-5

D104810

Dimethyldichlorosilane

≥98.5% (GC)

Core monomer for organosilicon polymers such as PDMS

TEOS / silicate ester precursors

78-10-4

T110593

Tetraethyl orthosilicate

Reagent grade, ≥98%

Reagent-grade TEOS; sol–gel and silica film precursor

TEOS / silicate ester precursors

78-10-4

T110596

Tetraethyl orthosilicate

≥99% (GC)

High-purity TEOS; precursor for electronic-grade coatings and materials

TEOS / silicate ester precursors

78-10-4

T110594

Tetraethyl orthosilicate

PrimorTrace™, ≥99.999% metals basis

TEOS with ultralow metals basis; for trace-metal-controlled systems

TEOS / silicate ester precursors

78-10-4

T110595

Tetraethyl orthosilicate (TEOS)

PrimorTrace™, ≥99.99% metals basis

High-purity, low-metals TEOS; for thin-film deposition and related uses

TEOS / silicate ester precursors

78-10-4

T434182

Tetraethyl orthosilicate

Packaged for deposition systems

Dedicated packaging for deposition systems

Silicone intermediates

556-67-2

O160041

Octamethylcyclotetrasiloxane (D4)

≥98% (GC)

Cyclic siloxane oligomer D4; key feedstock for silicone rubber/fluids

Silicone intermediates

541-05-9

H156955

Hexamethylcyclotrisiloxane (D3)

≥98% (GC)

Cyclic siloxane oligomer D3; PDMS chain-growth feedstock

Silicone intermediates

107-46-0

H105443

Hexamethyldisiloxane

≥99%

HMDSO; highly volatile siloxane for surface treatment/plasma cleaning

Silicone intermediates

107-46-0

H105444

Hexamethyldisiloxane

NMR grade, ≥99.7%

NMR-grade HMDSO: for spectroscopic testing sensitive to impurity peaks; may also serve as an internal standard/reference in certain systems (depending on method).

Silicone intermediates

999-97-3

H475794

Hexamethyldisilazane

99.9%

Strong hydrophobic surface treatment reagent; protecting-group reagent

Silicone intermediates

999-97-3

H106018

Hexamethyldisilazane (HMDS)

For GC derivatization, ≥99% (GC)

Common silylation reagent for GC derivatization, etc.

Silicone intermediates

69430-24-6

C194626

Cyclic polydimethylsiloxane

≥98%

Dimethyl cyclosiloxane mixture (DMC); intermediate for silicone fluid/rubber polymerization

Dimethyl silicone fluid

63148-62-9

D104763

Dimethyl silicone fluid

For oil bath, 180 °C

Silicone fluid for oil baths; suitable up to 180 °C

Dimethyl silicone fluid

63148-62-9

S1371822

Dimethyl silicone fluid

For oil bath, 30 °C to +250 °C

Wide-temperature-range oil-bath silicone fluid (30 °C to +250 °C)

Dimethyl silicone fluid

63148-62-9

D104762

Dimethyl silicone fluid

Viscosity 100 ± 8 mPa·s

General-purpose lubrication/anti-stick; 100 mPa·s

Dimethyl silicone fluid

63148-62-9

D104767

Dimethyl silicone fluid

Viscosity 1000 ± 80 mPa·s

High-viscosity grade for rheology modification

PMX-200 dimethyl silicone fluid

63148-62-9

S104742

PMX-200 dimethyl silicone fluid

~10 mPa·s, neat (25 °C)

Low-viscosity flow agent

PMX-200 dimethyl silicone fluid

63148-62-9

S104749

PMX-200 dimethyl silicone fluid

~100 mPa·s, neat (25 °C)

General formulation grade

PMX-200 dimethyl silicone fluid

63148-62-9

S104752

PMX-200 dimethyl silicone fluid

~1000 mPa·s, neat (25 °C)

High-viscosity grade for sealing/defoaming systems

PMX-200 dimethyl silicone fluid

63148-62-9

S104754

PMX-200 dimethyl silicone fluid

~60000 mPa·s, neat (25 °C)

Grease-like, ultra-high-viscosity system

Silicone fluid

63148-62-9

S433164

Silicone fluid

5 cSt (25 °C)

Low-viscosity silicone fluid (5 cSt) for lubrication/spreading

Silicone fluid

63148-62-9

S433163

Silicone fluid

100000 cSt (25 °C)

Ultra-high-viscosity silicone fluid (100000 cSt) for damping/sealing

Polydimethylsiloxane

63148-62-9

H431357

Polydimethylsiloxane

Viscosity 0.65 cSt (25 °C)

Ultra-low-viscosity PDMS for solvent-based/surface modification uses

Hydrogen silicone fluid

63148-57-2

P742455

Polymethylhydrosiloxane

15–40 mm²/s

PMHS containing Si–H; used for water-repellent finishing/crosslinking

Hydrogen silicone fluid

63148-57-2

P477954

Polymethylhydrosiloxane (trimethylsiloxy-terminated)

~3 cSt

Low-viscosity, trimethylsiloxy-terminated PMHS

Hydrogen silicone fluid

9004-73-3

P107083

Poly(methylhydrosiloxane)

15–40 mPa·s (20 °C)

Poly(methylhydrosiloxane); used as crosslinker/reducing agent

Silica powder

7631-86-9

S104573

Silicon dioxide

AR, Light

General AR-grade silica powder for routine laboratory use

Silica powder

7631-86-9

S104604

Silicon dioxide

≥99.9% metals basis

High-purity (low-metals) silica powder for high-purity materials/electronic uses

Mesoporous silica

7631-86-9

S433664

Mesoporous silicon dioxide

≥99% metals basis, SBA-15

SBA-15 mesoporous silica for materials research

Nano silica

7631-86-9

S104596

Nano silicon dioxide

≥99.5% metals basis, 30 nm

30 nm nano-silica; high-purity (low-metals) grade

Silica reference material

7631-86-9

S119594

Reference material for SSA, total pore volume, and pore diameter (mesoporous silica)

SSA: 511 m²/g; TPV: 0.806 cm³/g; pore diameter: 6.31 nm

Reference material for mesoporous silica SSA/porosity/pore size

Silica reference material

7631-86-9

S119579

Thermal analysis reference material (silica)

Phase transition temperature: 574.29 °C

Silica phase-transition-temperature reference material for thermal analysis

Silica standard solution

7631-86-9

S104579

Silicon dioxide standard solution

Analytical standard, 1000 µg/mL in 0.05 mol/L NaOH

1000 µg/mL silica standard solution for elemental analysis

Silica standard solution

7631-86-9

S104580

Silicon dioxide standard solution

Analytical standard, 100 mg/L in 0.05% NaCO

100 mg/L silica standard solution for water/environmental analysis

Silica crystal / bulk

7631-86-9

S140828

Silicon dioxide crystal

PrimorTrace™, ≥99.99% metals basis, Ø2 mm × 10 mm, cylinder

High-purity silica crystal cylinder for optics/reference materials

Silica micropowder

7631-86-9

S409422

Silica micropowder

≥99.7% metals basis, spherical, 28.5 µm

Spherical silica micropowder (28.5 µm) for fillers/rheology modification

Magnetic SiO microspheres (SLC)

7631-86-9

M120229

Core–shell magnetic silica microspheres (SLC)

Matrix: SiO; surface: SiOH; 45 µm; 10 mg/mL in PBS

–SiOH surface; 4–5 µm; general capture applications

Magnetic SiO microspheres (SLC)

7631-86-9

M120213

Core–shell magnetic silica microspheres (SLC)

Matrix: SiO; surface: NH; 34 µm; 10 mg/mL in PBS

–NH₂ surface; 34 µm; bio-conjugation

Magnetic SiO microspheres (SLC)

7631-86-9

M120218

Core–shell magnetic silica microspheres (SLC)

Matrix: SiO; surface: COOH; 34 µm; 10 mg/mL in PBS

–COOH surface; 3–4 µm; protein immobilization

Magnetic SiO microspheres (SLC)

7631-86-9

M120220

Core–shell magnetic silica microspheres (SLC)

Matrix: SiO; surface: Epoxy; 0.1–1 µm; 5 mg/mL in PBS

Epoxy surface; 0.1–1 µm; high specific surface area

Magnetic SiO microspheres (SLE)

7631-86-9

M120191

Embedded magnetic silica microspheres (SLE)

Matrix: SiO; surface: NH; 12 µm; 10 mg/mL

–NH₂ surface; 12 µm

Magnetic SiO microspheres (SLE)

7631-86-9

M120208

Embedded magnetic silica microspheres (SLE)

Matrix: SiO; surface: SiOH; 34 µm; 10 mg/mL in PBS

–SiOH surface; 3–4 µm

Magnetic SiO microspheres (SLE)

7631-86-9

M120198

Embedded magnetic silica microspheres (SLE)

Matrix: SiO; surface: COOH; 34 µm; 10 mg/mL in PBS

–COOH surface; 3–4 µm

Magnetic SiO microspheres (SLE)

7631-86-9

M120203

Embedded magnetic silica microspheres (SLE)

Matrix: SiO; surface: Epoxy; 34 µm; 10 mg/mL in PBS

Epoxy surface; 3–4 µm

Monodisperse SiO microspheres

7631-86-9

M120353

Monodisperse silica microspheres

300 nm; 2.5% (w/v) in ethanol

Bare monodisperse SiO microspheres; 300 nm; ethanol dispersion

Monodisperse SiO microspheres

7631-86-9

M120357

Monodisperse silica microspheres

2.0 µm; 2.5% (w/v) in ethanol

Bare monodisperse SiO microspheres; 2 µm; ethanol dispersion

Monodisperse SiO₂–NH microspheres

7631-86-9

M120371

Amino-functionalized monodisperse silica microspheres

Amino; 300 nm; 2.5% (w/v) in ethanol

Amino-functionalized microspheres for bio-conjugation

Monodisperse SiO₂–COOH microspheres

7631-86-9

M120362

Carboxyl-functionalized monodisperse silica microspheres

Carboxyl; 300 nm; 2.5% (w/v) in ethanol

Carboxyl-functionalized microspheres for protein/amine coupling carriers

Elemental silicon / bulk

7440-21-3

S108980

Silicon

PrimorTrace™, ≥99.99% metals basis, 1–3 mm

High-purity silicon lumps (1–3 mm) for materials and alloy research

Elemental silicon / powder

7440-21-3

S434691

Silicon

≥99.998% metals basis, powder, >60 mesh

Ultra-high-purity silicon powder (>60 mesh) for low-metals applications

Elemental silicon / powder

7440-21-3

S434690

Silicon

≥99% metals basis, powder, −325 mesh

General high-purity silicon powder (325 mesh)

Elemental silicon / powder

7440-21-3

S108981

Silicon

PrimorTrace™, ≥99.99% metals basis, 40–200 mesh

High-purity silicon powder (40–200 mesh), PrimorTrace™

Elemental silicon / powder

7440-21-3

S401567

Silicon powder

≥99.9% metals basis, 1–3 µm

High-purity micron silicon powder (1–3 µm) for fillers/sintering

Elemental silicon / powder

7440-21-3

S108978

Silicon powder

PureSpectra™, spectroscopic grade

PureSpectra™ spectroscopic-grade silicon powder for spectral/optical analysis

Elemental silicon / nano powder

7440-21-3

S278710

Nano silicon powder

≥99.9% metals basis, 60–100 nm

Nano silicon powder (60–100 nm) for nanomaterials research

Elemental silicon / target

7440-21-3

S434734

Silicon

PrimorTrace™, ≥99.999% metals basis, sputtering target, 2.00 in × 0.25 in

High-purity silicon sputtering target for thin-film deposition

Elemental silicon / single crystal wafer

7440-21-3

S434708

Silicon

Plate 40 × 40 mm, thickness 3.0 mm, single crystal, p-type, 100

Single-crystal silicon wafer 40 × 40 × 3 mm, p-type, for devices and teaching

Elemental silicon / standard solution

7440-21-3

S115456

Silicon standard solution

1000 µg/mL in 0.05 mol/L NaOH

1000 µg/mL silicon standard for elemental analysis/ICP

Elemental silicon / nano powder

7440-21-3

S434736

Silicon

Nano powder <100 nm (BET), <3% oxygen passivation

Nano silicon powder <100 nm with mild oxygen passivation

Typical Application Areas of Silicones

Application area

Main silicone material categories

Typical products / usage points

Role of silicones

Construction & infrastructure

Silicone rubber, silicone resins, silane coupling agents, water repellents/protectants

Curtain-wall structural adhesives, weatherproof sealants, door/window seals; exterior wall water repellents, stone protectants; waterproof coatings, silicone-modified weather-resistant coatings

Long-term weatherproof sealing, water/moisture resistance; improved coating durability and UV aging resistance; enhanced adhesion of coatings/adhesives to glass, metals, concrete, etc.

Electronics, power & new energy

Silicone gels and potting compounds, silicone rubber, thermally conductive silicone greases/fluids, silicone resins

Encapsulation of electronic modules/transformers/coils; thermal greases and thermally conductive potting compounds; insulating coatings, cable jackets, seals for power equipment

Electrical insulation, moisture protection, and vibration damping; thermal pathways for heat dissipation; reliability and service life under high temperature, high voltage, and hot-humid environments

Automotive & transportation

Silicone rubber, specialty fluorosilicone rubber, silicone resins, silicone fluids

Seals in engine bay and body; wire-harness jackets, ignition-coil potting; lamp sealing and waterproofing; weather-resistant sealing/bonding in interior parts; wipers and water strips

Maintains elasticity and sealing under heat, oil contamination, vibration, and outdoor exposure; improves waterproofing, dustproofing, and aging resistance; enhances interior weatherability and noise control

Personal care & daily chemicals

Silicone fluids, modified silicone fluids, silicone surfactants, film-forming silicones

Conditioning silicones in shampoos/conditioners; silicone film formers and SPF-boosting auxiliaries in sunscreens; long-wear waterproof feel enhancers in color cosmetics; slip agents in creams/serums

Improves skin/hair feel (smooth, soft, non-greasy); forms flexible breathable films for water/sweat resistance and long wear; enhances spreadability, application, and visual gloss

Healthcare & consumer products

Medical-grade silicone rubber, silicone gels, specialty silicone fluids

Medical catheters/drainage tubes/implant components; contact lenses, goggles, respirators; baby nipples/bottle parts; baking molds, seals, etc.

Leverages biostability, softness, and temperature resistance for safe, comfortable, washable, and sterilizable products; ensures stability and reliability during long-term human contact

Laboratory & research; industrial process control

Silicone defoamers, silicone fluids, silane coupling agents, RTV silicone rubber, potting compounds, silicone-based water/anti-stick coatings

Defoamers in reactors/fermentation/cleaning/wastewater; substrate surface treatment (silanes); sealing/insulation/potting under high temperature/strong UV/hot-humid conditions; formulation research for lubricity/anti-stick/waterproof coatings

Rapid foam knockdown and foam suppression for stable processes; improved adhesion/durability via coupling agents; reliable sealing/insulation/protection under harsh conditions; development of functional surfaces (anti-stick, water-repellent, anti-fouling, etc.)

 

Aladdin: https://www.aladdinsci.com/

Categories: Technical articles
Explore topics: Silicon Si

Da — when not otherwise indicated, molecular weight units are daltons.   Mw — weight-average molecular weight.   Mn — number-average molecular weight.

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Cite this article

Aladdin Scientific. "A Panoramic Guide to Silicone Materials: Structural Mechanisms, Core Properties, Value Chain, and Product Categories" Aladdin Knowledge Base, updated Dec 18, 2025. https://www.aladdinsci.com/us_en/faqs/a-panoramic-guide-to-silicone-materials-en.html
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