Ammonium persulfate(APS) - ACS, used for Ammonium persulfate can be used as an oxidizing reagent for the solvent-free oxidation of：Primary and secondary alcohols to corresponding carbonyl compounds in an aqueous medium.Thiols to disulfides.It can also be

CAS: 7727-54-0 Cat. No.: A112449 Formula: H₈N₂O₈S₂ Molecular Weight: 228.20 EC Number: 231-786-5

GRADE & PURITY ACS

Synonyms

Ammonium peroxodisulfate | PER | AP | APS

Storage

Protected from light,Room temperature

Shipped In

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Overview

Ammonium persulfateis a readily available oxidizing agent for various chemicaltransformations, and it is also usedas a bleaching agent in the chemical industry.

Specifications

Synonyms

Ammonium peroxodisulfate | PER | AP | APS

Specifications & Purity

ACS

Application

Ammonium persulfate can be used as an oxidizing reagent for the solvent-free oxidation of：Primary and secondary alcohols to corresponding carbonyl compounds in an aqueous medium.Thiols to disulfides.It can also be used as an initiator to initiate copolyme

Storage

Protected from light,Room temperature

Shipped In

FedEx DG Service

Grade

ACS

Names and Identifiers

Pubchem Sid

508816634

Canonical Smiles

[NH4+].[NH4+].[O-]S(=O)(=O)OOS(=O)(=O)[O-]

IUPAC Name

diazanium;sulfonatooxy sulfate

InChIKey

ROOXNKNUYICQNP-UHFFFAOYSA-N

INCHI

1S/2H3N.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h2*1H3;(H,1,2,3)(H,4,5,6)

Isomeric SMILES

[NH4+].[NH4+].[O-]S(=O)(=O)OOS(=O)(=O)[O-]

WGK Germany

1

RTECS

SE0350000

UN Number

1444

Packing Group

III

Molecular Weight

228.20

Reaxy-Rn

11343687

Reaxys-RN_link_address

https://www.reaxys.com/reaxys/secured/hopinto.do?context=S&query=IDE.XRN=11343687&ln=

Taxonomic Classification

Taxonomy Tree

• Kingdom Inorganic compounds
  • Superclass Homogeneous non-metal compounds
    • Class Non-metal oxoanionic compounds
      • Subclass Non-metal peroxodisulfates

• Kingdom: Inorganic compounds
• Superclass: Homogeneous non-metal compounds
• Class: Non-metal oxoanionic compounds
• Subclass: Non-metal peroxodisulfates
• Intermediate Tree Nodes: Not available
• Direct Parent: Non-metal peroxodisulfates
• Alternative Parents: Inorganic salts Inorganic oxides
• Molecular Framework: Not available
• Substituents: Non-metal peroxodisulfate - Inorganic oxide - Inorganic salt
• Description: This compound belongs to the class of inorganic compounds known as non-metal peroxodisulfates. These are inorganic non-metallic compounds containing a peroxodisulfate as its largest oxoanion.
• External Descriptors: Not available

Data sources

1. Djoumbou Feunang Y, Eisner R, Knox C, Chepelev L, Hastings J, Owen G, Fahy E, Steinbeck C, Subramanian S, Bolton E, Greiner R, and Wishart DS. ClassyFire: Automated Chemical Classification With A Comprehensive, Computable Taxonomy. Journal of Cheminformatics, 2016, 8:61.

DOI: 10.1186/s13321-016-0174-y

Chemical and Physical Properties

• Sensitivity: Light sensitive.Hygroscopic
• Refractive Index: 1.5
• Melt Point(°C): 120°C
• Molecular Weight: 228.210 g/mol
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 1
• Exact Mass: 227.972 Da
• Monoisotopic Mass: 227.972 Da
• Topological Polar Surface Area: 152.000 Ų
• Heavy Atom Count: 12
• Formal Charge: 0
• Complexity: 206.000
• Isotope Atom Count: 0
• Defined Atom Stereocenter Count: 0
• Undefined Atom Stereocenter Count: 0
• Defined Bond Stereocenter Count: 0
• Undefined Bond Stereocenter Count: 0
• The total count of all stereochemical bonds: 0
• Covalently-Bonded Unit Count: 3

XLogP3